Nole exits from doubles as well and that too in straight sets. But, as I mentioned before this is not an upset and is to the highest seed that is still alive in the doubles (no to mention they are from the host country).
Now that he is out of both singles and doubles, it remains to be seen whether he wants to take the next flight home or want to play with Anna. Interestingly, Anna can also take a flight right now. She is not entered in the doubles event and has lost in the first round of singles (not to mention that she just recently got married).